C Position | Compound 1 | Heteronuclear multiple bond correlation | |
---|---|---|---|
1HNMR (δ = ppm, J = Hz) | 13CNMR (ppm) (δ = ppm, J = Hz) | ||
1 | – | 110.6 | – |
2 | – | 156.3 | – |
3 | 6.13(d, J = 3.0) | 92.9 | C1, C2, C4, C5 |
4 | – | 161.8 | – |
5 | 6.3 (d, J = 2.5) | 95.0 | C1, C3, C4, C6 |
6 | – | 156.0 | – |
7 | – | 192.4 | – |
OCH3 | 3.73 (s) | 54.9 | C4 |
1′ | – | 129.8 | – |
2′ | 7.58 (d, J = 9.1) | 131.6 | C1′, C6’, C7 |
3′ | 6.78 (d, J = 8.4) | 114.8 | C1’, C4’, C5’ |
4′ | – | 160.9 | – |
5′ | 6.8 (d, J = 8,6) | 114.8 | C1′, C4′, C3′ |
6′ | 7.58 (d, J = 9.1) | 131.6 | C1′, C2′, C7 |
1′′ | 4.79 (d, J = 7.8) | 100.6 | C2 |
2′′ | 2.92 (dd, J = 3.9, 3.9) | 73.1 | C1′′; C 3′′ |
3′′ | 3.18 (dd, J = 5.9, 5.7) | 76.6 | C2′′; C4′′ |
4′′ | 3.01 (dd, J = 7.8, 4.6) | 69.7 | C5′′; C6′′ |
5′′ | 3.29 (m) | 77.1 | C6′′ |
6′′ | 3,39 (m) | 60,7 | C5′′ |