NO. | TR (min) | Formula | Found Mass | [M + H]− (Da) | Error (ppm) | Identification | Relative peak areas (× 106) | |
---|---|---|---|---|---|---|---|---|
ETB | EFB | |||||||
1 | 2.35 | C13H18O7 | 285.0977 | 161.0450, 123.0444, 105.0352 | −0.8 | gastrodin | 2.17 | 1.43 |
2 | 4.53 | C7H6O3 | 137.0248 | 137.0244, 108.0224, 92.0275 | 3.1 | p-hydroxybenzoic acid | – | 0.77 |
3 | 6.70 | C9H8O3 | 163.0406 | 145.8896, 119.0505, 93.0361 | 3.2 | 3-hydroxycinnamic acid | – | 0.43 |
4 | 7.01 | C34H32O8 | 567.2028 | 457.1678, 393.1388, 285.0978, 161.0454, 153.0573, 129.0579 | 0.6 | bleochranol D | – | 2.80 |
5 | 7.71 | C40H56O22 | 887.3179 | 707.2520, 619.2221, 439.1590 | −1.3 | dactylorhin A | 3.93 | 3.06 |
6 | 8.13 | C21H22O8 | 401.1228 | 284.0313, 255.0290, 238.0630, 227.0337, 195.0465 | −3.6 | 2,7-dihydroxy-4-methoxyphenanthrene-2-O-glucoside | – | – |
7 | 8.21 | C27H32O13 | 563.1747 | 540.6504, 429.8704, 394.1452, 320.7833, 310.8648 | −4.1 | 2,7-dihydroxy-4-methoxyphenanthrene-2,7-O-diglucoside | – | 1.18 |
8 | 9.62 | C34H46O17 | 725.2635 | 457.1673, 285.0954, 171.0654, 153.0551, 123.0451 | −3.8 | militarine | 30.48 | 38.39 |
9 | 9.76 | C20H22O6 | 357.1332 | 313.0688, 225.0513, 181.0614, 121.0287, 77.0403 | −3.3 | pinoresinol | – | – |
10 | 10.31 | C21H26O8 | 405.1537 | 243.1015, 227.0705, 201.0893, 136.0531, 122.0400 | −4.5 | 3′-hydroxy-5-methoxybibenzyl-3-O-β-D-glucopyranoside | 0.72 | 1.56 |
11 | 11.08 | C16H12O5 | 283.0601 | 237.0654, 211.0864, 75.0467 | −3.8 | 1,8-dihydroxy-3-methoxy-6-methylanthracene-9,10-dione | – | 1.53 |
12 | 12.15 | C15H13O4 | 256.0734 | 239.0345, 211.0401, 201.8356, 167.0496, 143.0501 | −3.0 | 7-hydroxy-2-methoxyphenanthrene-3,4-dione | – | – |
13 | 12.42 | C15H12O3 | 239.0714 | 224.0466, 196.0523, 167.0491 | 0.3 | 4-methoxyphenanthrene-2,7-diol | – | 1.92 |
14 | 12.99 | C16H14O4 | 269.0820 | 254.0563, 211.0388, 183.0448 | 0.2 | 2,7-dihydroxy-3,4-dimethoxyphenanthrene | – | 6.01 |
15 | 13.54 | C51H64O24 | 1059.3674 | 791.2752, 661.2301, 569.1989, 439.1569, 153.0557 | −3.8 | gymnoside X | 1.07 | 0.89 |
16 | 13.64 | C28H26O5 | 441.1691 | 347.1255, 253.0852, 241.0868, 211.0751, 93.0360 | −3.7 | shanciguol | – | 1.51 |
17 | 13.80 | C16H18O4 | 273.1126 | 243.1036, 227.0700, 185.0636, 136.0516, 122.0372, 106.0415 | −2.2 | 3,3′-dihydroxy-5,4′-dimethoxybibenzyl | – | – |
18 | 13.88 | C15H16O3 | 243.1026 | 227.0707, 183.0810, 136.0537, 93.0357 | −0.4 | 3,3′-dihydroxy-5-methoxybibenzyl | – | 1.80 |
19 | 14.07 | C22H20O4 | 347.1278 | 332.1024, 237.0561, 225.0549, 209.0622, 93.0352 | −3.2 | 4,7-dihydroxy-1-(p-hydroxybenzyl)-2-methoxy-9,10-dihydrophenanthrene | 0.32 | – |
20 | 14.26 | C29H24O5 | 451.1507 | 437.1341, 392.1347, 329.0777, 224.0484 | −9.8 | 1,8-bis(p-hydroxybenzyl)-4-methoxyphenanthrene-2,7-diol | – | 8.73 |
21 | 14.31 | C22H18O4 | 345.1124 | 330.0875, 302.0909, 237.0545 | −2.4 | 1-(p-hydroxybenzyl)-4-methoxyphenanthrene-2,7-diol | 0.25 | – |
22 | 14.50 | C25H24O6 | 419.1480 | 405.1118, 377.1172, 225.0548 | −4.8 | bleochranol B | 0.21 | 1.89 |
23 | 14.67 | C23H20O5 | 375.1225 | 360.0979, 317.0802, 224.0484 | −3.6 | bleformin B | – | 5.08 |
24 | 14.71 | C30H26O6 | 481.1631 | 465.1301, 434.1102, 419.1264, 225.0548 | −5.3 | blestrin A | 0.79 | 5.08 |
25 | 14.89 | C22H22O4 | 349.1434 | 243.1017, 227.0704, 183.0810, 93.0356 | −3.1 | 3,3′-dihydroxy-4-(p-hydroxybenzyl)-5-methoxybibenzyl | – | – |
26 | 14.94 | C30H24O6 | 479.1478 | 464.1236, 432.0980, 421.1041, 379.0948, 238.0631, 224.0478, 196.0533 | −4.6 | blestrin D | 0.46 | 1.91 |
27 | 15.53 | C32H26O8 | 537.1529 | 522.1312, 507.1027, 492.0773, 464.0849, 421.0668, 377.0799, 209.8293, 130.9680 | −4.9 | 4,8,4′,8′-tetramethoxy-[1,1′-biphenanthrene]-2,7,2′,7′-tetrol | 0.01 | 9.15 |
28 | 15.74 | C37H32O7 | 587.2047 | 571.1716, 543.1831, 527.1544, 476.1243, 449.1367, 434.1257, 270.2400, 224.0534, 152.9984 | −4.9 | bleformin D | – | 9.63 |
29 | 16.08 | C15H14O3 | 241.0869 | 226.0615, 183.0449, 169.0667 | −0.7 | 2,4-dimethoxyphenanthrene-7-ol | 0.13 | 1.48 |
30 | 16.49 | C27H26O7 | 461.1584 | 425.1723, 381.1463, 242.0897, 93.0338 | −4.7 | pleionesin C | 0.04 | 0.36 |
31 | 16.61 | C16H14O3 | 253.0862 | 238.0621, 223.0388, 195.0441, 167.0502 | −3.1 | 2-hydroxy-4,7-dimethoxyphenanthrene | 0.01 | 1.42 |
32 | 16.89 | C18H18O4 | 297.1126 | 253.0491, 239.0346, 225.0942, 211.0392, 166.0456 | −2.1 | 2,3,4,7-tetramethoxyphenanthrene | 0.01 | 2.28 |
33 | 16.94 | C29H26O5 | 453.1671 | 438.1428, 345.1106, 251.0712, 195.0470, 93.0362 | −8.2 | 2,7-dihydroxy-1,6-bis(p-hydroxybenzyl)-4-methoxy-9,10-dihydrophenanthrene | 0.10 | 0.64 |
34 | 17.46 | C23H24O4 | 363.1585 | 333.1163, 255.0940, 227.0706, 199.0746, 157.0631, 93.0378 | −4.7 | bulbocol | 0.15 | 3.85 |
35 | 17.67 | C22H22O3 | 333.1486 | 163.1126, 107.0521, 75.0477 | −3.2 | 5-hydroxy-2-(p-hydroxybenzyl)-3-methoxybibenzyl | 0.60 | 3.34 |
36 | 18.27 | C27H35O9 | 502.2211 | 369.2416, 337.2141, 193.1229, 163.1124, 147.0816, 133.1056 | 0.5 | (20S,22R)-1β,2β,3β,4β,5β,7α-hexahydroxyspirost-25 (27)-en-6-one | 9.14 | 1.06 |
37 | 18.30 | C18H30O3 | 293.2117 | 275.1976, 249.1821, 235.1714, 221.1501, 171.1030, 121.1041, 59.0153 | −1.7 | striatolide | – | 2.49 |
38 | 18.78 | C16H32O2 | 255.2327 | 238.027, 224.0464, 210.0314, 195.0444, 182.0355, 167.0502 | −1.0 | palmitic acid | – | 0.95 |
39 | 18.87 | C31H23O8 | 522.1329 | 508.1470, 493.1272, 450.1078, 253.0495, 225.0527, 210.0426 | 1.7 | 3′,7′,7-trihydroxy-2,2′,4′-trimethoxy-[1,8′-biphenanthrene]-3,4-dione | 7.20 | 0.76 |
Total | Â | Â | Â | Â | Â | Â | 57.79 | 123.37 |