peak | tR(min) | formula | MW | [M + H]+ | MS/MS | [M-H]− | MS/MS | Putative identity | reference |
---|---|---|---|---|---|---|---|---|---|
1 | 2.46 | C39H50O25 | 918.2641 | 919.2706 | 773, 611, 465, 303 | 917.2817 | 755, 609, 463, 462, 301, 300 | Quercetin 3-O-deoxyhexosyl-(1 → 6)-[deoxyhexosyl -(1 → 2)]-hexoside-7-O-hexoside | [19] |
2 | 3.20 | C39H50O24 | 902.2692 | 903.2755 | 757, 595, 449, 287 | 901.2599 | 739, 593, 447, 446, 285, 284 | Kaempferol 3-O-deoxyhexosyl-(1 → 6)-[deoxyhexosyl -(1 → 2)]- hexoside-7-O-hexoside (compound 1) | [19] |
3 | 3.67 | C33H40O21 | 772.2062 | 773.2111 | 627, 465, 303 | 771.1976 | 609, 463, 301 | Quercetin 3-O-deoxyhexosyl -(1 → 6)-hexoside − 7-O-hexoside | [19] |
4 | 4.78 | C33H40O20 | 756.2113 | 757.2175 | 611, 449, 287, 228 | 755.2016 | 593, 447, 285 | Kaempferol 3-O-deoxyhexosyl -(1 → 6)-hexoside − 7-hexoside | [20] |
5 | 5.25 | C34H42O21 | 786.2219 | 787.2267 | 641, 479, 317 | 785.2145 | 623, 477, 315 | Isorhamnetin 3-O- deoxyhexosyl -(1 → 6)-hexoside − 7-O-hexoside | [19] |
6 | 7.21 | C33H40O19 | 740.2164 | 741.2215 | 595, 449, 287 | 739.2073 | 593, 285, 284 | Kaempferol 3-O-deoxyhexosyl -(1 → 6)-[deoxyhexosyl-(1 → 2)]-hexoside (compound 2) | [19] |
7 | 7.48 | C34H42O20 | 770.2269 | 771.2328 | 625, 479, 317 | 769.2176 | 623, 315, 314 | 3-O- deoxyhexosyl -(1 → 6)-[deoxyhexosyl -(1 → 2)]- hexoside | [19] |
8 | 7.64 | C27H30O16 | 610.1534 | 611.1610 | 465, 303 | 609.1450 | 463, 301, 300 | Quercetin 3-O-deoxyhexosyl -(1 → 6)-hexoside | [19] |
9 | 9.08 | C27H30O15 | 594.1585 | 595.1665 | 449, 287 | 593.1495 | 447, 285 | Kaempferol 3-O-deoxyhexosyl -(1 → 6)-hexoside | [19] |
10 | 9.53 | C28H32O16 | 624.169 | 625.1756 | 479, 317 | 623.1609 | 477, 315 | Isorhamnetin 3-O-deoxyhexosyl -(1 → 6)-hexoside | [19] |