Precisiona and accuracyb | Polyphenolic compounds | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
GA1 | CAT2 | ChA3 | ECAT4 | CA5 | UMB6 | CoA7 | RUT8 | EA9 | QUE10 | KAE11 | |
Intraday (n = 9) | |||||||||||
 Day 1 | |||||||||||
  Average area | 9,498,108 | 1,587,143 | 2,536,193 | 2,519,193 | 4,619,983 | 1,549,082 | 9,747,582 | 2,579,650 | 1,499,363 | 2,429,518 | 782,051 |
  ±SD | 15,273 | 15,413 | 18,257 | 20,705 | 34,228 | 15,372 | 66,280 | 14,123 | 11,745 | 8846 | 2835 |
  %RSD | 0.161 | 0.971 | 0.720 | 0.822 | 0.741 | 0.992 | 0.680 | 0.547 | 0.783 | 0.364 | 0.363 |
  %Recovery | 99.9 | 99.8 | 99.7 | 99.4 | 99.7 | 99.5 | 99.7 | 99.8 | 99.0 | 99.9 | 99.9 |
 Day 2 | |||||||||||
  Average area | 9,488,221 | 1,589,559 | 2,529,570 | 2,519,830 | 4,625,180 | 1,551,030 | 9,751,220 | 2,579,215 | 1,496,578 | 2,428,618 | 782,443 |
  ±SD | 24,151 | 12,751 | 24,681 | 22,101 | 37,601 | 16,210 | 68,152 | 12,489 | 12,930 | 9764 | 3956 |
  %RSD | 0.255 | 0.802 | 0.976 | 0.877 | 0.813 | 1.05 | 0.699 | 0.484 | 0.864 | 0.402 | 0.505 |
  %Recovery | 99.8 | 99.9 | 99.4 | 99.4 | 99.8 | 99.6 | 99.8 | 99.8 | 98.8 | 99.8 | 100 |
 Day 3 | |||||||||||
  Average area | 9,501,364 | 1,586,062 | 2,541,010 | 2,522,814 | 4,629,476 | 1,548,746 | 9,743,617 | 2,582,113 | 1,503,104 | 2,432,157 | 782,007 |
  ±SD | 16,429 | 14,829 | 24,319 | 24,128 | 34,215 | 14,814 | 74,613 | 12,056 | 13,689 | 7955 | 2245 |
  %RSD | 0.173 | 0.935 | 0.957 | 0.956 | 0.739 | 0.957 | 0.766 | 0.467 | 0.911 | 0.327 | 0.287 |
  %Recovery | 99.9 | 99.7 | 99.9 | 99.5 | 99.9 | 99.4 | 99.7 | 99.9 | 99.2 | 100 | 99.9 |
Interday (n = 27) | |||||||||||
 3 Days with 9 replicates per day | |||||||||||
  Average area | 9,495,898 | 1,587,588 | 2,535,591 | 2,520,612 | 4,624,880 | 1,549,619 | 9,747,473 | 2,580,326 | 1,499,682 | 2,430,098 | 782,167 |
  ±SD | 14,065 | 14,331 | 25,336 | 23,613 | 36,348 | 16,041 | 71,681 | 13,849 | 13,280 | 9962 | 3142 |
  %RSD | 0.148 | 0.903 | 0.999 | 0.937 | 0.786 | 1.04 | 0.735 | 0.537 | 0.852 | 0.410 | 0.401 |
  %Recovery | 99.8 | 99.8 | 99.6 | 99.4 | 99.8 | 99.5 | 99.7 | 99.9 | 99.0 | 99.9 | 100 |