Table 4 Concentrations (mg/g unless otherwise indicated) of Gurigumu-7 constituents in the three fractions

Safflower

protocatechuic acid

0.00 ± 0.00

1.61 ± 0.01

1.15 ± 0.00

hydroxysafflor yellow A

nd

12.77 ± 0.01

0.19 ± 0.02

6-hydroxykaempfer 3,6,7-triglucoside

0.17 ± 0.00

2.09 ± 0.00

0.08 ± 0.01

kaempferol-3-O-D-glucoside

nd

0.082 ± 0.04

3.13 ± 0.01

bidenoside C

nd

nd

8.75 ± 0.01

kaempferol-3-O-rutinocoside

0.06 ± 0.01

0.65 ± 0.05

2.86 ± 0.04

6-hydroxykaempferol-3-rutinoside-6-glucoside

nd

1.63 ± 0.02

0.22 ± 0.02

6-hydroxykaempferol-3,6-diglucoside

nd

0.28 ± 0.039

0.04 ± 0.03

linolic acid

nd

0.21 ± 0.03

26.2 ± 0.09

α-linolenic acid

nd

0.20 ± 0.08

25.5 ± 0.13

oleic acid

0.36 ± 0.07

0.38 ± 0.10

3.13 ± 0.09

Fructus chebulae

chebulic acid

12.81 ± 0.02

0.74 ± 0.00

0.076 ± 0.00

gallic acid

7.68 ± 0.02

12.23 ± 0.02

nd

chebumeinin A

0.09 ± 0.00

0.67 ± 0.01

0.09 ± 0.00

chebumeinin B

0.24 ± 0.01

0.48 ± 0.01

0.24 ± 0.01

casuarinin

nd

2.35 ± 0.01

1.88 ± 0.01

corilagin

3.48 ± 0.01

7.30 ± 0.02

3.50 ± 0.02

chebulagic acid

2.25 ± 0.01

6.05 ± 0.01

2.38 ± 0.01

pentagalloyl glucose

0.86 ± 0.01

1.06 ± 0.01

0.94 ± 0.02

ellagic acid

nd

82.14 ± 0.80

297.97 ± 1.84

Flos scabiosae

caffeic acid

nd

0.46 ± 0.00

nd

quinic acid

nd

2.28 ± 0.01

nd

chlorogenic acid

0.87 ± 0.01

32.08 ± 0.58

0.83 ± 0.02

p-coumaric acid

0.24 ± 0.00

0.34 ± 0.00

0.67 ± 0.01

luteolin-6-C-glucoside

nd

5.54 ± 0.01

0.64 ± 0.01

quercetin-3-glucoside

nd

0.98 ± 0.01

4.30 ± 0.01

rutin

nd

nd

0.05 ± 0.00

apigenin-7-arabinoglucoside

nd

0.75 ± 0.00

5.38 ± 0.02

apigenin-4′-glucoside

nd

nd

11.59 ± 0.02

apigenin-7-glucoside

nd

nd

11.51 ± 0.01

luteolin-4′-O-glucoside

nd

0.73 ± 0.00

16.02 ± 0.02

luteolin-7-O-glucoside

nd

0.84 ± 0.01

16.12 ± 0.02

luteolin

nd

nd

2.96 ± 0.02

apigenin

nd

nd

1.59 ± 0.01

ursolic acid

nd

nd

14.91 ± 0.35

hederagenin/3β,23-dihydroxyursan-12-en-28-oic acid

0.01 ± 0.019

0.01 ± 0.02

1.80 ± 0.03

Herba ephedrae

Ephadra alkaloids

nd

98.33 ± 0.15 %^a

1.67 ± 0.64 %^a

Proanthocyanidin A2 equivalent

nd

31.33 ± 2.62

15.64 ± 1.78

Herba violae

6,7-dihydroxycoumarin

nd

25.23 ± 0.74

3.12 ± 0.02

5,5′-bi (6,7-dihydroxycoumarin)

nd

0.67 ± 0.01

nd

apigenin 6,8-di-C-β-D-glucoside,

0.54 ± 0.53 %^a

90.81 ± 1.01 %^a

8.65 ± 0.87 %^a

apigenin 6-C-β-D-glucosyl-8-C- α-L-arabinoside/apigenin 6-C-β- D- glucosyl-8-C-β-L-arabinoside

2.88 ± 0.36 %^a

48.96 ± 0.08 %^a

48.16 ± 0.65 %^a

apigenin 6-C-α-L-arabinosyl- 8-C-β-D-xyloside/apigenin 6,8-di-C-α-L-arabinoside

2.66 ± 0.08 %^a

47.50 ± 0.45 %^a

49.83 ± 0.71 %^a

Caulis clematidis armandii

calceolarioside B

0.18 ± 0.89

0.17 ± 0.07