Table 1 1H and 13C-NMR and Chemical Shifts of compound (ppm, CDCl3, 500 and 100 MHz, respectively).
C. No | Multiplicity (DEPT) | 13C-NMR | 1H (J= Hz) |
|---|---|---|---|
1 | CH2 | 38.5 | 1.71(m # of H), 1.93(m, #of H) |
2 | CH2 | 32.3 | 1.59 m, 1.83 m |
3 | CH | 72.4 | 3.44 br m (w 1/2 = 12.5) |
4 | CH2 | 43.0 | 2.21 dd, 2.23 dd |
5 | C | 140.8 | ------ |
6 | CH | 121.8 | 5.53 br d (5.0) |
7 | CH2 | 32.8 | 1.81 m, 1.97 m |
8 | CH | 31.8 | 1.61 m |
9 | CH | 51.7 | 0.95 m |
10 | C | 36.5 | ------ |
11 | CH2 | 22.0 | 1.01 m, 1.42 m |
12 | CH2 | 40.9 | 1.69 m, 1.40 m |
13 | C | 41.3 | ------ |
14 | CH | 57.8 | 1.09 m |
15 | CH2 | 32.7 | 1.49 m, 1.63 m |
16 | CH | 82.2 | 4.39 q like (7.5) |
17 | CH | 63.7 | 1.75 m |
18 | CH3 | 19.8 | 1.06 s |
19 | CH3 | 14.9 | 0.80 s |
20 | CH | 29.9 | 1.60 m |
21 | CH3 | 17.5 | 0.72 d (J 21,20 = 6.5) |
22 | CH2 | 33.2 | 1.2 dd (overlapped), 1.50 dd (overlapped) |
23 | C | 110.5 | ------ |
24 | CH | 42.9 | 1.84 dd (5.5, 4.5) |
25 | CH2 | 32.4 | 1.65 m, 1.81 m |
26 | CH2 | 67.9 | 3.35 m, 3.42 m |
27 | CH3 | 16.8 | 0.95 d (J 27,24 = 6.5) |